FDSOI channel control by implanted high-k buried oxide

ABSTRACT

Methods of locally changing the BOX layer of a MOSFET device to a high-k layer to provide different Vts with one backside voltage and the resulting device are provided. Embodiments include providing a Si substrate having a BOX layer formed over the substrate and a SOI layer formed over the BOX layer; implanting a high current of dopants into at least one portion of the BOX layer; performing a high-temperature anneal of the BOX layer; forming first and second fully depleted silicon-on-insulator (FDSOI) transistors on the SOI layer, the first FDSOI transistors formed above either the BOX layer or the at least one portion of the BOX layer and the second FDSOI transistors formed above the at least one portion of the BOX layer; and applying a single voltage across a backside of the Si substrate.

RELATED APPLICATION

The present application is a Divisional of application Ser. No. 15/269,023, filed on Sep. 19, 2016, which is incorporated herein by reference in its entirety.

TECHNICAL FIELD

The present disclosure relates to formation of metal oxide field effect transistor (MOSFET) devices for integrated circuits (ICs). The present disclosure is particularly applicable to MOSFET devices formed with a fully depleted silicon-on-insulator (FDSOI) channel.

BACKGROUND

FDSOI process technology includes a continuous buried oxide (BOX) layer common to all devices on a wafer. One of the core benefits of FDSOI is the ability to control threshold voltage (Vt) by controlling backside voltages. However, an IC device may include different devices, e.g., an input/output (I/O) device, etc., formed on the same wafer, which have different trade-offs for channel control, subthreshold slope, and operating voltage. The device tradeoffs are typically set by adjustments to the gate oxide and threshold implants, but on FDSOI, this is also possible through bias to the backgate.

It would therefore be advantageous to have a methodology enabling formation of multiple devices with different Vts on a wafer with better channel control and the resulting device.

SUMMARY

An aspect of the present disclosure is a process of locally changing the dielectric constant, or k-value, of a BOX layer of a MOSFET device to provide different Vts with one backside voltage.

Another aspect of the present disclosure is a MOSFET device including a BOX layer having different k-values.

Additional aspects and other features of the present disclosure will be set forth in the description which follows and in part will be apparent to those having ordinary skill in the art upon examination of the following or may be learned from the practice of the present disclosure. The advantages of the present disclosure may be realized and obtained as particularly pointed out in the appended claims.

According to the present disclosure, some technical effects may be achieved in part by a method including: providing a silicon (Si) substrate having a BOX layer formed over the substrate and a silicon-on-insulator (SOI) layer formed over the BOX layer; implanting a high current of dopants into at least one portion of the BOX layer; performing a high-temperature anneal of the BOX layer; forming first and second fully depleted silicon-on-insulator (FDSOI) transistors on the SOI layer, the first FDSOI transistors formed above either the BOX layer or the at least one portion of the BOX layer and the second FDSOI transistors formed above the at least one portion of the BOX layer; and applying a single voltage across a backside of the Si substrate.

Aspects of the present disclosure include forming the BOX layer of silicon oxide (SiO_(x), 1<x<3). Other aspects include controlling a Vt of each of the first and second FDSOI transistors based on whether a FDSOI transistor is formed over the BOX layer or the at least one portion of the BOX layer and on a concentration of the implanted dopant in the at least one portion of the BOX layer underlying the FDSOI transistor. Further aspects include implanting the high current of dopants into the at least one portion of the BOX layer by: forming a photoresist layer over the SOI layer; patterning the photoresist layer; performing a high-current implant through the photoresist layer; and removing the photoresist layer prior to performing the high-temperature anneal. Other aspects include the at least one implanted portion of the BOX layer being implanted with different dopants under the first and second FDSOI transistors. Another aspect includes applying different voltages to the backside of the Si substrate based on different BOX regions above the substrate. Additional aspects include implanting a high current of multiple dopants of a same species with different implant energies into the at least one portion of the BOX layer. Other aspects include implanting the dopant at a dosage of 5e15 per centimeter squared (cm²) to 1e17/cm². Further aspects include selecting the dosage based on a desired Vt for the FDSOI transistor. Another aspect includes implanting multiple portions of the BOX layer, each portion at a different dosage for a different Vt. Additional aspects include the dopant being hafnium (Hf), zirconium (Zr), titanium (Ti), or tantalum (Ta).

Another aspect of the present disclosure is a MOSFET device including: a SOI layer over a Si substrate; first and second FDSOI transistors formed on the SOI layer; formed between the SOI layer and the Si substrate, wherein the BOX layer below the first FDSOI transistors is either implanted with a first dopant, forming a high-k layer, or is non-implanted, and the BOX layer below the second FDSOI transistors is implanted with a second dopant, forming a high-k layer, the first and second dopants being different; and a backgate region formed on a bottom surface of the substrate.

Aspects of the device include the BOX layer being SiO_(x), 1<x<3. Other aspects include the high-K layer being hafnium silicon oxide (HfSiO_(x), 1<x<3), zirconium silicon oxide (ZrSiO_(x), 1<x<3), titanium silicon oxide (TiSiO_(x), 1<x<3), or tantalum silicon oxide (TaSiO_(x), 1<x<3). Further aspects include the HfSiO_(x), 1<x<3, ZrSiO_(x), 1<x<3, TiSiO_(x), 1<x<3, or TaSiO_(x), 1<x<3 layer being formed with a dosage of 5e15/cm² to 1e17/cm² of Hf, Zr, Ti, Ta, respectively.

A further aspect of the present disclosure is a method including: providing a Si substrate having a SiO_(x), 1<x<3 BOX layer formed over the substrate and a SOI layer formed over the SiO_(x), 1<x<3 BOX layer, the SiO_(x), 1<x<3 BOX layer having a substantially uniform thickness; forming a photoresist layer over the SOI layer; patterning the photoresist layer; implanting at least one portion of the SiO_(x), 1<x<3 BOX layer with a Hf, Zr, Ti, Ta dopant at a dosage of 5e15 per cm² to 1e17/cm² through the patterned photoresist layer; stripping the photoresist layer; annealing the SiO_(x), 1<x<3 BOX layer; forming shallow trench isolation (STI) regions through the SOI and/or SiO_(x), 1<x<3 BOX layers; forming first FDSOI transistors on the SOI layer above either the SiO_(x), 1<x<3 BOX layer or the at least one implanted portion of the SiO_(x), 1<x<3 BOX layer; forming second FDSOI transistors on the SOI layer above the at least one implanted portion of the SiO_(x), 1<x<3 BOX layer; and applying a single voltage across a backside of the Si substrate.

Aspects of the present disclosure include controlling a Vt of each of the first and second FDSOI transistors based on whether a FDSOI is formed over the SiO_(x), 1<x<3 BOX layer or the at least one portion of the SiO_(x), 1<x<3 BOX layer and on a concentration of the implanted dopant in the SiO_(x), 1<x<3 BOX layer underlying the FDSOI transistor. Further aspects include selecting the dosage based on a desired Vt for the FDSOI transistor. Another aspect includes implanting multiple portions of the SiO_(x), 1<x<3 BOX layer, each portion at a different dosage for a different Vt. Additional aspects include the at least one implanted portion of the SiO_(x), 1<x<3 BOX layer being implanted with different dopants under the first and second FDSOI transistors.

Additional aspects and technical effects of the present disclosure will become readily apparent to those skilled in the art from the following detailed description wherein embodiments of the present disclosure are described simply by way of illustration of the best mode contemplated to carry out the present disclosure. As will be realized, the present disclosure is capable of other and different embodiments, and its several details are capable of modifications in various obvious respects, all without departing from the present disclosure. Accordingly, the drawings and description are to be regarded as illustrative in nature, and not as restrictive.

BRIEF DESCRIPTION OF THE DRAWINGS

The present disclosure is illustrated by way of example, and not by way of limitation, in the figures of the accompanying drawing and in which like reference numerals refer to similar elements and in which:

FIGS. 1 through 4 schematically illustrate a process of locally changing the BOX layer of a MOSFET device to a high-k layer to provide different Vts with one backside voltage, in accordance with an exemplary embodiment.

DETAILED DESCRIPTION

In the following description, for the purposes of explanation, numerous specific details are set forth in order to provide a thorough understanding of exemplary embodiments. It should be apparent, however, that exemplary embodiments may be practiced without these specific details or with an equivalent arrangement. In other instances, well-known structures and devices are shown in block diagram form in order to avoid unnecessarily obscuring exemplary embodiments. In addition, unless otherwise indicated, all numbers expressing quantities, ratios, and numerical properties of ingredients, reaction conditions, and so forth used in the specification and claims are to be understood as being modified in all instances by the term “about.”

The present disclosure addresses and solves the current problem of respective trade-offs for channel control, subthreshold slope, and operating voltage attendant upon forming a common BOX layer for different FDSOI MOSFET devices.

Methodology in accordance with embodiments of the present disclosure includes providing a Si substrate having a BOX layer formed over the substrate and a SOI layer formed over the BOX layer. A high current of dopants is implanted into at least one portion of the BOX layer. A high-temperature anneal of the BOX layer is performed. First and second FDSOI transistors are formed on the SOI layer, the first FDSOI transistors are formed above either the BOX layer or the at least one portion of the BOX layer and the second FDSOI transistors are formed above the at least one portion of the BOX layer. A single voltage is applied across a backside of the Si substrate.

Still other aspects, features, and technical effects will be readily apparent to those skilled in this art from the following detailed description, wherein preferred embodiments are shown and described, simply by way of illustration of the best mode contemplated. The disclosure is capable of other and different embodiments, and its several details are capable of modifications in various obvious respects. Accordingly, the drawings and description are to be regarded as illustrative in nature, and not as restrictive.

FIGS. 1 through 4 (cross-sectional views) schematically illustrate a process of locally changing the BOX layer of a MOSFET device to a high-k layer to provide different Vts with one backside voltage, in accordance with an exemplary embodiment. Adverting to FIG. 1, a BOX layer 101 is formed, e.g., to a thickness of 1 nm to 100 nm, over a bulk Si substrate 103. The BOX layer 101 may be formed, e.g., of SiO_(x), 1<x<3, e.g., silicon dioxide (SiO₂), oxygen (O₂) deficient SiO_(x) (SiO_(x), 1<x<2), or Si deficient SiO_(x) (SiO_(x), 2<x<3). A SOI layer 105 is formed over the BOX layer 101. The method may begin by providing an already formed SOI substrate including substrate 103, BOX layer 101, and SOI layer 105. Next, a photoresist layer 201 is formed over the SOI layer 105 and patterned, as depicted in FIG. 2.

Adverting to FIG. 3, a high-current implant is performed through the photoresist layer 201 (as illustrated by the arrows 301) to implant at least one portion of the BOX layer 101 with a dopant, e.g., Hf, Zr, Ti, or Ta. As a result, a high-k BOX layer 303 is formed. The high-k BOX layer 303 may be formed, e.g., of HfSiO_(x), 1<x<3, ZrSiO_(x), 1<x<3, TiSiO_(x), 1<x<3, TaSiO_(x), 1<x<3; HfSiO_(x), 1<x<2, ZrSiO_(x), 1<x<2, TiSiO_(x), 1<x<2, TaSiO_(x), 1<x<2; or HfSiO_(x), 2<x<3, ZrSiO_(x), 2<x<3, TiSiO_(x), 2<x<3, TaSiO_(x), 2<x<3, depending on the dopant and on the composition of the BOX layer 101. The energy of the high-current implant is specifically adjusted to peak the implant in the BOX layer 101. The dopant is implanted, e.g., at a dosage of 5e15cm² to 1e17/cm², and the particular dosage is selected based on a desired Vt for a subsequently formed FDSOI transistor. The higher the dose selected, the higher the Vt of the subsequently formed gate. Further, multiple portions of the BOX layer may be implanted at different dosages (not shown for illustrative convenience) to achieve a different Vt for each subsequently formed FDSOI transistor. Thereafter, the photoresist layer 201 is stripped, and a high-temperature anneal of the BOX layers 101 and 303 is performed, e.g., at a temperature of 1000° C. to 1400° C. Alternatively, multiple high-current implants of the same species, e.g., Hf, Zr, Ti, or Ta, could be performed with different implant energies to evenly dope the BOX layer 101.

A photoresist layer (not shown for illustrative purposes) could also be formed over the SOI layer 105 and patterned to protect the high-k BOX layer 303. Thereafter, a second high-current implant (not shown for illustrative convenience) could be performed through the photoresist layer to implant the non-implanted portion of the BOX layer 101 with a dopant different from the dopant that was used to implant the BOX layer 303, e.g., Hf, Zr, Ti, or Ta. Consequently, two different high-k BOX layers may be formed, thereby covering the entire wafer.

FDSOI transistors 401 and 403 are then formed simultaneously on the SOI layer 105. The FDSOI transistor 401 is formed above either a non-implanted portion of the BOX layer 101 or an implanted portion (not shown for illustrative convenience) and the FDSOI transistor 403 is formed on the SOI layer 105 above an implanted portion of the BOX layer 101, e.g., the high-k BOX layer 303, as depicted in FIG. 4. In the instance where the FDSOI transistors 401 and 403 are both formed on the SOI layer 105 over implanted portions of the BOX layer 101, the implanted portions of the BOX layer 101 would not be formed from the same dopants. The FDSOI transistors 401 and 403 each include a gate 405, spacers 407, and a dielectric layer 409. It should be noted that the FDSOI transistors 401 and 403 are rudimentarily depicted for illustrative purposes and are not complete. Thereafter, S/D regions 411 are formed on opposite sides of each FDSOI transistor 401 and 403. A STI region 413 may also be formed through the SOI layer 105 and the non-implanted and/or implanted portions of the BOX layer. Last, a single voltage may be applied across a backside of the Si substrate 103 through the backgate 415 to provide different Vts for the FDSOI transistors 401 and 403. Alternatively, different back biases may be applied in combination with different BOX regions to provide different Vts.

The embodiments of the present disclosure can achieve several technical effects including locally varying backgate control of the channel; achieving a wider range for Vt control (from ultra-high Vt (uHVt) to ultra-low Vt (uLVt)), higher sensitivity of Vt change to backgate voltage, and lower subthreshold slope; and enabling the k-value of the BOX layer to be varied early in the process flow through implantation of Hf, Zr, Ti, or Ta. Embodiments of the present disclosure enjoy utility in various industrial applications as, for example, microprocessors, smart phones, mobile phones, cellular handsets, set-top boxes, DVD recorders and players, automotive navigation, printers and peripherals, networking and telecom equipment, gaming systems, and digital cameras. The present disclosure therefore has industrial applicability in any IC devices with MOSFETs having a FDSOI channel.

In the preceding description, the present disclosure is described with reference to specifically exemplary embodiments thereof. It will, however, be evident that various modifications and changes may be made thereto without departing from the broader spirit and scope of the present disclosure, as set forth in the claims. The specification and drawings are, accordingly, to be regarded as illustrative and not as restrictive. It is understood that the present disclosure is capable of using various other combinations and embodiments and is capable of any changes or modifications within the scope of the inventive concept as expressed herein. 

What is claimed is:
 1. A metal oxide field effect transistor (MOSFET) device comprising: a silicon-on-insulator (SOI) layer formed over a silicon (Si) substrate; first and second fully depleted silicon-on-insulator (FDSOI) transistors formed on the SOI layer; a buried oxide (BOX) layer formed between the SOI layer and the Si substrate, wherein the BOX layer below the first FDSOI transistors is non-implanted, and the BOX layer below the second FDSOI transistors is implanted with a second dopant, forming a high-k layer; and a backgate region formed on a bottom surface of the substrate, wherein the high-K layer comprises hafnium silicon oxide (HfSiO_(x), 1<x<3), zirconium silicon oxide (ZrSiO_(x), 1<x<3), titanium silicon oxide (TiSiO_(x), 1<x<3), or tantalum silicon oxide (TaSiOx, 1<x<3).
 2. The device according to claim 1, wherein the BOX layer comprises silicon oxide (SiO_(x), 1<x<3).
 3. The device according to claim 1, wherein the HfSiO_(x), 1<x<3, ZrSiO_(x), 1<x<3, TiSiO_(x), 1<x<3, or TaSiO_(x), 1<x<3 layer is formed with a dosage of 5e15 per centimeter square (cm²) to 1e17/cm² of halfnium (Hf), zirconium (Zr), titanium (Ti), or tantalum (Ta), respectively.
 4. A device comprising: a silicon (Si) substrate having a buried oxide (BOX) layer formed over the substrate and a silicon-on-insulator (SOI) layer formed over the BOX layer; high current of dopants implanted into at least one portion of the BOX layer; first and second fully depleted silicon-on-insulator (FDSOI) transistors formed on the SOI layer, wherein the BOX layer below the first FDSOI transistors is implanted with a first dopant, forming a high-k layer, and the BOX layer below the second FDSOI transistors is implanted with a second dopant, forming a high-k layer, the first and second dopants being different; and a backgate region formed on a bottom surface of the Si substrate, wherein the second dopant comprises hafnium (Hf), zirconium (Zr), titanium (Ti), or tantalum (Ta).
 5. The device according to claim 4, wherein the BOX layer comprises silicon oxide (SiO_(x), 1<x<3).
 6. The device according to claim 4, wherein a threshold voltage (Vt) of each of the first and second FDSOI transistors is controlled based on whether a FDSOI transistor is formed over the BOX layer or the at least one portion of the BOX layer and on a concentration of the implanted dopants in the at least one portion of the BOX layer underlying the FDSOI transistor.
 7. The device according to claim 4, wherein different voltages are applied to the backside of the Si substrate based on different BOX regions above the substrate.
 8. The device according to claim 4, wherein a high current of multiple dopants of a same species with different implant energies are implanted into the at least one portion of the BOX layer.
 9. The device according to claim 4, the dopant is implanted at a dosage of 5e15 per centimeter squared (cm²) to 1e17/cm².
 10. The device according to claim 9, wherein the dosage is selected based on a desired Vt for the FDSOI transistor.
 11. The device according to claim 4, multiple portions of the BOX layer are implanted, each portion at a different dosage for a different Vt.
 12. A device comprising: a silicon (Si) substrate having a silicon oxide (SiO_(x), 1<x<3) buried oxide (BOX) layer formed over the substrate and a SOI layer formed over the SiO_(x), 1<x<3 BOX layer, the SiO_(x), 1<x<3 BOX layer having a substantially uniform thickness; at least one portion of the SiO_(x), 1<x<3 BOX layer implanted with a dopant; shallow trench isolation (STI) regions through the SOI and/or the SiO_(x), 1<x<3 BOX layers; and first and second fully depleted silicon-on-insulator (FDSOI) transistors formed on the SOI layer, the first FDSOI transistors formed above either the SiO_(x), 1<x<3 BOX layer or the at least one implanted portion of the SiO_(x), 1<x<3 BOX layer and the second FDSOI transistors formed above the at least one implanted portion of the SiO_(x), 1<x<3 BOX layer, wherein the dopant comprises halfnium (Hf), zirconium (Zr) titanium (Ti), or tantalum (Ta).
 13. The device according to claim 12, wherein a threshold voltage (Vt) of each of the first and second FDSOI transistors is controlled based on whether a FDSOI transistor is formed over the SiO_(x), 1<x<3 BOX layer or the at least one portion of the SiO_(x), 1<x<3 BOX layer and on a concentration of the implanted dopant in the SiO_(x), 1<x<3 BOX layer underlying the FDSOI transistor.
 14. The device according to claim 12, wherein the dosage is selected based on a desired Vt for the FDSOI transistor.
 15. The device according to claim 12, wherein multiple portions of the SiO_(x), 1<x<3 BOX layer are implanted, each portion at a different dosage for a different Vt.
 16. The device according to claim 12, wherein the at least one implanted portion of the SiO_(x), 1<x<3 BOX layer is implanted with different dopants under the first and second FDSOI transistors.
 17. The device according to claim 12, wherein the dopant includes a dosage of 5e15 per centimeter square (cm²) to 1e17/cm². 